The site in question:
Framework: Pagelines (this framework is usually not an issue for jetpack publicize and may not necessarily factor into the problem here)
Plugin in question:
Publicize: http://littleriverband.com/wp-admin/options-general.php?page=sharing
is not authorizing. After it attempts to do so it throws a 404 – I tried twitter and Facebook – both failed
URLs returned that 404’ed:
In the end there was no authorization made.